Geochemistry: Exploration, Environment, Analysis; August 2003; v. 3; no. 3;
p. 245-261; DOI: 10.1144/1467-7873/03-008
© 2003 Geological Society of London
PbZn(As) Enrichments in Amphibolites from Broken Hill-Type Ore Systems, NW Queensland: Products of Retrograde Hydrothermal Dispersion
Patrick J. Williams and
Michael J. Smith
Economic Geology Research Unit,
School of Earth Sciences, James Cook University, Townsville,
Q4811, Australia(e-mail
Patrick.Williams@jcu.edu.au)
Amphibolites
typically lacking visual signs of PbZn mineralization are
associated with pelitic gneisses at the Cannington and Maramungee
Broken Hill-type PbZnAg deposits in the
eastern Mount Isa Inlier. Within 150 m of the sulphide-rich
lodes these have consistently anomalously high chalcophile metal
contents. The enrichments broadly mimic the primary distinctions
between the two deposits in respect to the relative abundances of Zn,
As and Pb. At Maramungee, metal concentrations of thin amphibolites
broadly increase towards the mineralized rock body and comparison with
data from gneisses illustrates the general superiority of basic rocks
as a sample medium due to their inherently low Pb-content and
comparatively homogenous primary chemistry. Most amphibolite at
Cannington occurs in a single metamorphosed sill that is consistently
anomalous, though with irregular chalcophile element distributions.
Petrographic and SEM studies show that the metal enrichments are
related to sulphides in complex retrograde parageneses which have
selectively replaced metamorphic (calcic) plagioclase. Most galena
occurs as sub-10 µm grains. Chalcophile elements were
dispersed in a hydrous fluid and selectively enriched in the
amphibolites during retrograde metamorphism under greenschist to
sub-greenschist facies conditions. Routine analysis of basic rocks for
Pb (and Zn) might therefore provide a simple proximity indicator for
Broken Hill-type deposits, especially in poorly exposed terrains where
amphibolites are the most common cause of magnetic anomalies tested by
exploration
drilling.
KEYWORDS: lead, zinc, dispersion, Broken
Hill-type, amphibolite
Copyright © 2009 by Geological Society of London